Advanced search
Publication Cover
Journal of Coordination Chemistry Volume 64, 2011 - Issue 24
Submit an article Journal homepage
251
Views
9
CrossRef citations to date
0
Altmetric
Original Articles

Self-assembly of three supramolecular architectures based on an unsymmetrical N-heterocyclic ligand

Wenjuan Chu Department of Chemistry, Zhengzhou University, Zhengzhou 450052, Henan, P.R. China
,
Xinhua Lou College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, P.R. China
,
Zhiyuan Wang Department of Chemistry, Zhengzhou University, Zhengzhou 450052, Henan, P.R. China
,
Chunying Xu Department of Chemistry, Zhengzhou University, Zhengzhou 450052, Henan, P.R. China
,
Yaoting Fan Department of Chemistry, Zhengzhou University, Zhengzhou 450052, Henan, P.R. ChinaCorrespondence[email protected]
&
Hongwei Hou Department of Chemistry, Zhengzhou University, Zhengzhou 450052, Henan, P.R. China
Pages 4373-4382 | Received 12 Sep 2011, Accepted 20 Oct 2011, Published online: 05 Dec 2011
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

Three new compounds, {[Cd(Htmb)(Cl)(CH3CO2)] · CH3OH} n (1), [Cd(Htmb)2(Cl)2(H2O)2] · 4H2O (2), and [Cd(Htmb)2(I)2] (3) (Htmb = 2-(1H-triazol-1-ylmethyl)-1H-benzoimidazole), have been synthesized and characterized by elemental analysis, IR, and X-ray diffraction. Compound 1 features 1-D infinite double chains with space group and further forms a 3-D supramolecular structure by hydrogen bonds and π–π interactions. Compound 2 displays a mononuclear structure with space group P2/c, wherein an interesting water chain is formed. Compound 3 shows a mononuclear structure with space group P21/n and extends into a 3-D supramolecular structure through hydrogen bonds and π–π interactions. In addition, the spectral properties are investigated, with strong luminescence observed for 1 and 2.

Acknowledgments

This work was supported by the National Natural Science Foundation of China (Nos. 21171147 and 20871106) and the China National Key Basic Research Special Funds (No. 2009CB220005).

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Influence of the anion on the coordination mode of an unsymmetrical N-heterocyclic ligand in Cd(II) complexes: From discrete molecule to one- and two-dimensional structures
Source: Elsevier BV
Clathration of Two-Dimensional Coordination Polymers: Synthesis and Structures of [M(4,4'-bpy)(2)(H(2)O)(2)](ClO(4))(2).(2,4'-bpy)(2).H(2)O and [Cu(4,4'-bpy)(2)(H(2)O)(2)](ClO(4))(4).(4,4'-H(2)Bpy) (M = Cd(II), Zn(II) and bpy = Bipyridine).
Source: American Chemical Society (ACS)
Impact of counteranion on the self-assembly of Cd(II)-containing MOFs: Syntheses, structures and photoluminescent properties
Source: Elsevier BV
Syntheses, structures and luminescence of three cadmium coordination polymers based on 1,2-bis(1,2,4-triazol-1-ylmethyl)benzene
Source: Informa UK Limited
Engineering coordination polymers towards applications
Source: Royal Society of Chemistry (RSC)
Reactions of Alkoxycarbonylcarbenoids with Imidazole; An Improved Preparation of Ethyl Imidazole-1-ylacetate and the First Synthesis of Diethyl Imidazole-1-ylmalonate
Source: Georg Thieme Verlag KG
Structure and Magnetic Properties of a Hydroxo-Bridged Copper(II) Distorted Cubane Stabilized via Supramolecular Hydrogen Bonding with an Ionic Hexafluoroacetylacetonate
Source: American Chemical Society (ACS)
Zinc complex of bipyridine crown macrocycle: Luminescence sensing of anions in aqueous media via the cooperative action of metal-ligand and hydrophobic interactions
Source: Elsevier BV
CCDC 843264: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
A novel dodecanuclear cadmium(II) macrocycle with a 3D framework: synthesis, structure and properties
Source: Royal Society of Chemistry (RSC)
Synthesis and Crystal Structures of Co(II) Complexes Derived From Two Unsymmetrical Bis-Heterocyclic Ligands With Benzimidazole Moiety
Source: Informa UK Limited
A critical account on π–π stacking in metal complexes with aromatic nitrogen-containing ligands
Source: Royal Society of Chemistry (RSC)
Syntheses, crystal structures, and fluorescent properties of two 2-D Cd(II) complexes based on 2-((1H-1,2,4-triazol-1-yl)methyl)-1H-benzimidazole and 1,2,4,5-benzenetetracarboxylate
Source: (:unav)
Two- and three-dimensional coordination complexes constructed by 2-(1H-imidazol-1-methyl)-1H-benzimidazole: syntheses, structures, and fluorescent properties
Source: (:unav)
Crystal structures and luminescence properties of two Cd(II) complexes based on 2-(1H-imidazol-1-methyl)-6-methyl-1H-benzimidazole
Source: Walter de Gruyter GmbH
Two New Nonlinear Optical and Ferroelectric Three-Dimensional Metal−Organic Frameworks with an sqp-net
Source: American Chemical Society (ACS)
CCDC 843265: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Reversible Anion Exchanges of Porous Metal−Organic Frameworks: Syntheses and Structures of Silver Complexes with Novel Rigid Tripodal Nitrogen Ligands
Source: American Chemical Society (ACS)
Encapsulated Diverse Water Aggregates in Two Ag(I)/4,4 '-Bipyridine/Dicarboxylate Hosts: 1D Water Tape and Chain
Source: American Chemical Society (ACS)
CCDC 843263: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Syntheses, crystal structures, and fluorescent properties of two d10 metal complexes based on 2-(benzoimidazol-yl)methyl)-1H-1,2,4-triazole and 1,3,5-benzenetricarboxylate
Source: (:unav)
Formation of a decameric water ring in a cryptand-phthalic acid supramolecular adduct
Source: American Chemical Society (ACS)
Synthesis, Crystal Structure, Photoluminescent, and Electrochemical Properties of a Novel 2-D silver(I) Coordination Polymer with 1H-1,2,4-Triazole-1-Methylene-1H-Benzimidazole-1-Acetic Acid
Source: Springer Science and Business Media LLC
CCDC 843262: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.