Advanced search
Publication Cover
Journal of Coordination Chemistry Volume 65, 2012 - Issue 1
Submit an article Journal homepage
120
Views
10
CrossRef citations to date
0
Altmetric
Original Articles

A 3-D supramolecular compound based on Keggin-type polyoxometalates and potassium-sulfanilamide

Jiang Wu Key Laboratory of Design and Synthesis of Functional Materials and Green Catalysis, Colleges of Heilongjiang Province, Harbin Normal University, Harbin 150080, P. R. China
,
Chunxiao Wang Key Laboratory of Design and Synthesis of Functional Materials and Green Catalysis, Colleges of Heilongjiang Province, Harbin Normal University, Harbin 150080, P. R. ChinaCorrespondence[email protected]
,
Kai Yu Key Laboratory of Design and Synthesis of Functional Materials and Green Catalysis, Colleges of Heilongjiang Province, Harbin Normal University, Harbin 150080, P. R. China
,
Zhanhua Su Key Laboratory of Design and Synthesis of Functional Materials and Green Catalysis, Colleges of Heilongjiang Province, Harbin Normal University, Harbin 150080, P. R. China
,
Yang Yu Key Laboratory of Design and Synthesis of Functional Materials and Green Catalysis, Colleges of Heilongjiang Province, Harbin Normal University, Harbin 150080, P. R. China
,
Yanglei Xu Key Laboratory of Design and Synthesis of Functional Materials and Green Catalysis, Colleges of Heilongjiang Province, Harbin Normal University, Harbin 150080, P. R. China
&
Baibin Zhou Key Laboratory of Design and Synthesis of Functional Materials and Green Catalysis, Colleges of Heilongjiang Province, Harbin Normal University, Harbin 150080, P. R. ChinaCorrespondence[email protected]
 show all
Pages 69-77 | Received 26 Sep 2011, Accepted 04 Nov 2011, Published online: 06 Dec 2011
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

A Keggin-type polyoxometalate and potassium-sulfanilamide complex, [{K(C6H10N2O2S)2(H2O)}2(SiW12O40)2] · 2H3O+ · 10H2O (1), has been synthesized and characterized by elemental analyses, IR, TG, and single-crystal X-ray diffraction. Compound 1 exhibits infinite 1-D dimer chains which are constructed from Keggin units [α-SiW12O40]4− bridged by potassium-sulfanilamide fragments. These 1-D chains are linked via π–π interactions between benzene rings of the sulfanilamides to form 2-D layers, which are further packed into 3-D supramolecular assemblies through hydrogen bonds. The electrochemical and electrocatalytic behaviors of 1 have been studied in detail.

Acknowledgments

This work is supported by the National Natural Science Foundation of China (Grants 20671026 and 20971032), the Study Technological Innovation Project Special Foundation of Harbin (2009RFXXG202), and Technological Innovation Team Building Program of College of Heilongjiang Province (2009td04) and Innovation Team Research Program of Harbin Normal University (KJTD200902).

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Bond‐valence parameters obtained from a systematic analysis of the Inorganic Crystal Structure Database
Source: International Union of Crystallography (IUCr)
Synthesis and Structure of Two Keggin-Type Heteropolyanions: [VMo12O40]3n-n (1) and [H3PMoVMoVI11O40]1- (2)
Source: Springer Science and Business Media LLC
Synthesis, characterization and catalytic activity of a Wilkinson's type metal-organic–polyoxometalate hybrid compound
Source: Royal Society of Chemistry (RSC)
Porous organic-inorganic assemblies constructed from Keggin polyoxometalate anions and calix[4]arene-Na+ complexes: structures and guest-sorption profiles.
Source: Wiley
A novel 2D layered network based on 13-vanadomanganate(IV): K3(HABOB)4[MnV13O38] · 9H2O (ABOB = N-amidino-4-morpholincarboxamidine)
Source: Elsevier BV
Keggin-type mono lacunary silicotungstate supported onto zirconia: synthesis, characterization, and esterification reaction
Source: Informa UK Limited
α-Keggin tungstogermanate-supported transition metal complexes: hydrothermal synthesis, characterization, and magnetism of Cu2(phen)4(GeW12O40) and [Ni2(bpy)4(H2O)2(GeW12O40)]⋅2H2O
Source: (:unav)
Assembly of a new Keggin polyoxometalate-templated complex using flexible 1,2-bis(imidazol-1′-yl)ethane ligand
Source: Informa UK Limited
Present General Status of Understanding of Heteropoly Electrolytes and a Tracing of Some Major Highlights in the History of Their Elucidation
Source: American Chemical Society (ACS)
Solid-State Coordination Chemistry: The Self-Assembly of Microporous Organic–Inorganic Hybrid Frameworks Constructed from Tetrapyridylporphyrin and Bimetallic Oxide Chains or Oxide Clusters
Source: Wiley
A water chain with trimeric/hexameric clusters trapped in a POM/Ln compound
Source: Informa UK Limited
Porous organic-inorganic assemblies constructed from Keggin polyoxometalate anions and calix[4]arene-Na+ complexes: structures and guest-sorption profiles.
Source: Wiley
Hybrid Organic–Inorganic 1D and 2D Frameworks with ε-Keggin Polyoxomolybdates as Building Blocks
Source: HAL CCSD
1D‐Polyoxometalate‐Based Composite Compounds − Design, Synthesis, Crystal Structures, and Properties of [{Ln(NMP)6}(PMo12O40)]n (Ln = La, Ce, Pr; NMP = N‐methyl‐2‐pyrrolidone)
Source: Wiley
Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines
Source: VCH PUBLISHERS INC
Two new supramolecular assemblies based on Keggin-type polyoxometalates through Ag...O and π...π stacking interactions
Source: Elsevier BV
The synthesis of polyoxometalate-based metal-organic frameworks under ionothermal conditions
Source: Informa UK Limited
[Cu5Cl(4,4′-bipy)5][SiW12O40] · 1.5H2O: A novel three-dimensional framework constructed from polyoxometalate clusters and trinuclear Cu(I) complex
Source: Elsevier BV
Oxygen-17 nuclear magnetic resonance spectroscopy of polyoxometalates. 1. Sensitivity and resolution
Source: American Chemical Society (ACS)
Two supramolecular structures constructed from Keggin-type polyoxometalates and 4,4′-bipyridine
Source: Informa UK Limited
New potassium ion-bridged chainlike assembly from bisupporting Keggin units: K[M(phen)2(H2O)]2[PW12O40] · 2H2O (M=Fe, Cu)
Source: Elsevier BV
A twofold interpenetrating 3D Keggin-based Ag(I) complex based on a flexible bis-pyridyl-bis-amide
Source: Informa UK Limited
The Electrochemical Behavior of Keggin Polyoxometalate Modified by Tricyclic, Aromatic Entity
Source: Wiley
A Novel Chainlike Heteropolyanion Formed by Keggin Units: Synthesis and Structure of (ET)8n[PMnW11O39]n · 2nH2O
Source: Wiley
A series of POM-based hybrid materials with different copper/aminotriazole motifs
Source: Elsevier BV
Cobalt(II) complexes of the antibiotic sulfadiazine, the X-ray single crystal structure of [Co(C10H9N4O2S)2(CH3OH)2]
Source: Elsevier BV
Synthesis and structure of a new polyoxometalate-based inorganic–organic hybrid and application as a chemically bulk-modified electrode
Source: Informa UK Limited
Hybrid Molecular Materials Based upon Magnetic Polyoxometalates and Organic π-Electron Donors: Syntheses, Structures, and Properties of Bis(ethylenedithio)tetrathiafulvalene Radical Salts with Monosubstituted Keggin Polyoxoanions
Source: HAL CCSD
Bis[N1-(2-pyrimidinyl)sulphanilamido]zinc–ammonia (1/2), [Zn(C10H9N4O2S)2].2NH3
Source: International Union of Crystallography (IUCr)
A new polymeric chain formed by paradodecatungstate clusters and [Cu(en)2]2+ complexes: hydrothermal synthesis and characterization of [Cu(en)2]3[{Cu(en)2}2(H2W12O42)].12H2O
Source: (:unav)
Polyoxometalates: Very large clusters - Nanoscale magnets
Source: American Chemical Society (ACS)
Main-Group Element, Organic, and Organometallic Derivatives of Polyoxometalates.
Source: American Chemical Society (ACS)
Coordination behavior of sulfa-drugs: Synthesis, structural, and spectroscopic investigation on M(II) (N1-pyrimidin-2YL-sulfanilamido)2· × H2O
Source: Elsevier BV
Two organic–inorganic hybrids based on polyoxometalates: synthesis, crystal structure, and characterization
Source: Informa UK Limited
Assembly of three supramolecular compounds based on [P2Mo5O23]6− and Ni(II) complexes
Source: (:unav)
Cationic Mn12 single-molecule magnets and their polyoxometalate hybrid salts.
Source: American Chemical Society (ACS)
Synthesis and characterization of two novel high-dimensional extended structures based on Keggin-type polyoxometalates and potassium–glycine complex subunits
Source: Elsevier BV
CCDC 811837: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Solid State Coordination Chemistry: One-, Two-, and Three-Dimensional Materials Constructed from Molybdophosphonate Subunits Linked through Binuclear Copper Tetra-2-pyridylpyrazine Groups
Source: American Chemical Society (ACS)
Ionothermal synthesis and characterization of two new heteropolytungstates with 1-ethyl-3-methylimidazolium bromide ionic liquid as solvent
Source: Informa UK Limited
A Novel Organic−Inorganic Hybrid Based on an 8-Electron-Reduced Keggin Polymolybdate Capped by Tetrahedral, Trigonal Bipyramidal, and Octahedral Zinc: Synthesis and Crystal Structure of (CH3NH3)(H2bipy)[Zn4(bipy)3(H2O)2MoV8MoVI4O36(PO4)]·4H2O
Source: American Chemical Society (ACS)

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.