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Journal of Coordination Chemistry Volume 65, 2012 - Issue 2
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Original Articles

Hydrothermal synthesis, structure, and properties of lead(II)-based coordination compounds with R-isophthalic acid (R=OH, CH3)

Zhen Wang Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi’an 710069, China
,
Qing Wei Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi’an 710069, China
,
Gang Xie Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi’an 710069, China
,
Qi Yang Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi’an 710069, China
,
Sanping Chen Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi’an 710069, ChinaCorrespondence[email protected]
&
Shengli Gao Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi’an 710069, China
Pages 286-297 | Received 25 Aug 2011, Accepted 27 Oct 2011, Published online: 20 Jan 2012
 
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Abstract

Three new lead(II)-based coordination polymers, [Pb(5-OH-BDC)] n  · nH2O (1) (5-OH-BDC = 5-hydroxyisophthalate), [Pb2(5-CH3-BDC)2] n (2), and [Pb2(5-CH3-BDC)2(phen)2] n  · 2nH2O (3) (5-CH3-BDC = 5-methylisophthalate, phen = 1,10-phenanthroline), have been hydrothermally synthesized, structurally determined by single-crystal X-ray diffraction, and characterized by elemental analyses, IR spectra, and thermogravimetric analyses. Both 1 and 2 exhibit 2-D double-layer network structures, while 3 possesses 1-D chain structure bridged by 5-CH3-BDC. The coordination sphere of Pb(II) in 1 is holodirected, whereas in 2 and 3 the spheres feature hemidirected structures. Fluorescence properties of 1–3 have been investigated in the crystalline state at room temperature.

Acknowledgments

We gratefully acknowledge the financial support from the National Natural Science Foundation of China (Grant No. 20873100 and 21173168) and the Nature Science Foundation of Shaanxi Province (Grant Nos. FF10091 and SJ08B09).

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