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Journal of Coordination Chemistry Volume 65, 2012 - Issue 2
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Original Articles

Indium(III) complexes containing bithiazole derivatives, chloride, methanol, and dimethyl sulfoxide: X‐ray studies, spectroscopic characterization, and thermal analyses

Anita Abedi Department of Chemistry, North Tehran Branch, Islamic Azad University, Tehran, Iran
,
Nasser Safari Department of Chemistry, Shahid Beheshti University, G. C., Evin, Tehran 983963113, IranCorrespondence[email protected]
,
Vahid Amani Department of Chemistry, Shahid Beheshti University, G. C., Evin, Tehran 983963113, Iran
&
Hamid Reza Khavasi Department of Chemistry, Shahid Beheshti University, G. C., Evin, Tehran 983963113, Iran
Pages 325-338 | Received 03 Oct 2011, Accepted 30 Nov 2011, Published online: 20 Jan 2012
 
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Abstract

[In(dm4bt)Cl3(MeOH)] · 0.5dm4bt (1) (dm4bt is 2,2′‐dimethyl‐4,4′‐bithiazole) and [In(4bt)Cl3(MeOH)] (2) (4bt is 4,4′‐bithiazole) were prepared from the reaction of 4,4′‐bithiazole and 2,2′‐dimethyl‐4,4′‐bithiazole with InCl3 · 4H2O in methanol, respectively. [In(4bt)Cl3(DMSO)] (3) was also prepared from recrystallization of 2 in DMSO. These complexes were characterized by IR, UV‐Vis, 1H NMR, 13C{1H} NMR, and luminescence spectroscopy and their structures were studied by single‐crystal X‐ray crystallography. The thermal stabilities of 1 and 3 were studied by thermogravimetric and differential thermal analyses.

Acknowledgments

We thank the Graduate Study Councils of Islamic Azad University, North Tehran Branch and Shahid Beheshti University for the financial support.

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