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Journal of Coordination Chemistry Volume 65, 2012 - Issue 3
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Original Articles

Polyoxomolybdate(VI) anion stabilized by ammonium cation via CS2 elimination from N-benzyl-N-methylferrocenyl dithiocarbamate

Abhinav Kumar Faculty of Science, Department of Chemistry, University of Lucknow, Lucknow 226 007, India
,
Vikram Singh Faculty of Science, Department of Chemistry, Banaras Hindu University, Varanasi 221 005, India
,
Ajit N. Gupta Faculty of Science, Department of Chemistry, Banaras Hindu University, Varanasi 221 005, India
,
Manoj K. Yadav Faculty of Science, Department of Chemistry, Banaras Hindu University, Varanasi 221 005, India
,
Vinod Kumar Faculty of Science, Department of Chemistry, Banaras Hindu University, Varanasi 221 005, India
&
Nanhai Singh Faculty of Science, Department of Chemistry, Banaras Hindu University, Varanasi 221 005, IndiaCorrespondence[email protected]
Pages 431-438 | Received 21 Sep 2011, Accepted 09 Dec 2011, Published online: 24 Jan 2012
 
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Abstract

A new polyoxomolybdate [(FcCH2)NH2(CH2C6H5)]4[Mo8O26] has been obtained by the reaction of ammonium molybdate and potassium N-benzyl-N-methylferrocenyl dithiocarbamate in mild acidic condition. The resulting cluster has been characterized by microanalyses, electronic absorption, photoluminescence, IR, and 1H NMR spectroscopy, and its electrochemical properties. Quantum chemical calculations have been performed in order to explain the CS2 elimination from the dithiocarbamate moiety. Single-crystal X-ray analysis of this compound reveals that the ammonium cation generates an intricate 2-D supramolecular architecture.

Acknowledgments

The authors are grateful to Council of Scientific and Industrial Research, New Delhi for the financial assistance in the form of Project No: 01(2290)/09/EMR-II, VS for (CSIR-SRF) and SAP Department of Chemistry, Banaras Hindu University for providing computational facility.

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