Advanced search
Publication Cover
Journal of Coordination Chemistry Volume 66, 2013 - Issue 5
Submit an article Journal homepage
145
Views
5
CrossRef citations to date
0
Altmetric
Original Articles

Two threefold interpenetrated metal-organic frameworks (CoII, NiII) with (65.8) topology constructed from biphenyl-3,4′-dicarboxylic acid

Zhong Sun College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, China
,
Yuanshuai Ding College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, China
,
Laijin Tian College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, ChinaCorrespondence[email protected]
&
Xiutang Zhang College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, China; Department of Chemistry and Chemical Engineering, Qilu Normal University, Jinan, ChinaCorrespondence[email protected]
Pages 763-771 | Received 19 Jul 2012, Accepted 01 Oct 2012, Published online: 12 Mar 2013
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

[Co(bmib)(bpda)]·H2O (1) and [Ni(bmib)(bpda)] (2) (H2bpda = biphenyl-3,4′-dicarboxylic acid; bmib = 4,4′-bis(2-methylimidazol-1-ylmethyl)benzene) were synthesized under hydrothermal conditions. The structures have been determined by single-crystal X-ray diffraction analyzes and further characterized by elemental analyzes, IR, PXRD, and TGA. Compounds 1 and 2 possess a threefold interpenetrated (65.8) architecture that incorporates left- and right-handed helical chains. The difference of angles between the coordination spacers in 1 and 2 causes a large difference along the c-axis.

Acknowledgements

The work was supported by financial support from the Natural Science Foundation of China (Grant No. 21101097), Natural Science Foundation of Shandong Province (ZR2010BQ023), and Qilu Normal University is acknowledged.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

A Series of Four-Connected Entangled Metal–Organic Frameworks Assembled from Pamoic Acid and Pyridine-Containing Ligands: Interpenetrating, Self-Penetrating, and Supramolecular Isomerism
Source: American Chemical Society (ACS)
Synthesis, crystal structures and photoluminescence of three new Mn(II) coordination polymers assembled from 2,4′-diphenic acid
Source: Informa UK Limited
Group 12 metal coordination polymers of 1,2-bis(diphenylphosphino)ethane dioxide: A persistent 1D chain motif and consequent 2D and 3D architectures
Source: Elsevier BV
Syntheses, structures, and properties of two- and three-dimensional coordination polymers based on bis(imidazole) and glutarate ligands
Source: Taylor & Francis
Homo- and heterometallic complexes based on polytopic carboxylic acid: synthesis, characterization, and property
Source: Informa UK Limited
Two Coordination Polymers Involving Triangular and Linear Trinuclear Co(II) Clusters Created Via In situ Ligand Synthesis
Source: American Chemical Society (ACS)
Design and syntheses of two threefold interpenetrating 2-D networks
Source: Informa UK Limited
A Molecular Basketwork: Self-Assembly of Coordination Polymers from Zn(II) and Biphenyl-3,4′-dicarboxylate Regulated by Different Flexible Bridging and Chelating N-Donor Ancillary Ligands
Source: American Chemical Society (ACS)
Syntheses, crystal structures, and properties of five mixed-ligand coordination polymers based on novel quaterphenyl-2,5,2′,5′-tetracarboxylic acid ligand
Source: Royal Society of Chemistry (RSC)
Two Azolium Rings Are Better Than One: A Strategy for Controlling Catenation and Morphology in Zn and Cu Metal–Organic Frameworks
Source: American Chemical Society (ACS)
A Metal−Organic Nanotube Exhibiting Reversible Adsorption of (H2O)12 Cluster
Source: (:unav)
Three 1-D complexes generated from a ferrocenyl carboxylate cadmium(II) precursor through substitution reactions of N-containing ligands: Syntheses, crystal structures and electrochemical properties
Source: Elsevier BV
Exploratory syntheses, structures, and photoluminescent properties of three lead multi-dimensional frameworks
Source: Informa UK Limited
New Examples of Metal Coordination Architectures of 3,3′,4,4′-Biphenyltetracarboxylic Acid – Syntheses, Crystal Structures, and Physical Properties
Source: Wiley
Supramolecular Isomerism of Metal-Organic Frameworks Derived from a Bicarboxylate Linker with Two Distinct Binding Motifs
Source: American Chemical Society (ACS)
A Dynamic Microporous Metal–Organic Framework with BCT Zeolite Topology: Construction, Structure, and Adsorption Behavior
Source: American Chemical Society (ACS)
Syntheses, structures, and luminescence of coordination compounds based on N-containing polycarboxylates
Source: Informa UK Limited
Synthesis and crystal structures of three new complexes derived from 3-(pyridin-3′-yl)-5-(pyridin-2′′-yl)-1,2,4-triazole
Source: Informa UK Limited
Preparation and gas adsorption studies of three mesh-adjustable molecular sieves with a common structure.
Source: American Chemical Society (ACS)
Syntheses and crystal structures of two Co(II) coordination polymers based on 4,6-bis(4-methylbenzoyl)isophthalic acid and 4,4′-bipyridine
Source: Informa UK Limited
Solvent-Controlled Rare Case of a Triple Helical Molecular Braid Assembled from Proton-Transferred Sebacic Acid
Source: American Chemical Society (ACS)
Recent Advances in s-Block Metal Carboxylate Networks
Source: American Chemical Society (ACS)
Substituent effect of R-isophthalates (R = –H, –CH3, –OCH3, –tBu, –OH, and –NO2) on the construction of CdII coordination polymers incorporating a dipyridyl tecton 2,5-bis(3-pyridyl)-1,3,4-oxadiazole
Source: (:unav)
Two square grid coordination polymers with manganese(II) and 1,4-bis(imidazole-1-ylmethyl)benzene
Source: Royal Society of Chemistry (RSC)
CCDC 886756: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
CCDC 886755: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Functional porous coordination polymers.
Source: Wiley
A novel 2D (3,5)-connected coordination framework with Zn2(COO)3 SBU
Source: Elsevier BV
Structural diversity of a series of urea-based coordination complexes: from water tapes, water-sulfate chains, to supramolecular structures
Source: Taylor & Francis
Molecular engineering for synthesizing novel structures of metal–organic frameworks with multifunctional properties
Source: Elsevier BV
Simultaneous self-assembly of a cage-like silver(I) complex encapsulating an Ag6 neutral cluster core and carbon dioxide fixation.
Source: (:unav)
Synthesis, structural characterization and thermal properties of three copper(II) complexes based on aryl hydrazide ligands
Source: Springer Science and Business Media LLC
Supramolecular Isomerism in Cadmium Hydroxide Phases. Temperature-Dependent Synthesis and Structure of Photoluminescent Coordination Polymers of α- and β-Cd2(OH)2(2,4-pyda)
Source: (:unav)
Crystal engineering of NLO materials based on metal-organic coordination networks
Source: American Chemical Society (ACS)
Syntheses, structures, and properties of a series of 2D and 3D coordination polymers based on trifunctional pyridinedicarboxylate and different (bis)imidazole bridging ligands
Source: Royal Society of Chemistry (RSC)

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.