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Journal of Coordination Chemistry Volume 66, 2013 - Issue 6
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Articles

Crystal structure and magnetic properties of Co(II) coordination polymer with CsCl-like topology

Xiao-Qing Zhao College of Life and Basic Sciences, Sichuan Agricultural University, Ya’an, 625014, P.R. ChinaCorrespondence[email protected]
&
Yun-Chun Li College of Life and Basic Sciences, Sichuan Agricultural University, Ya’an, 625014, P.R. China
Pages 937-945 | Received 16 Jun 2012, Accepted 13 Nov 2012, Published online: 21 Mar 2013
 
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Abstract

One Co(II) coordination polymer with 4-hydroxypyridine-2,6-dicarboxylic acid (H3L)-[Co1.5L(H2O)4]n (1) has been fabricated under hydrothermal condition through reaction of Co(OH)2 and H3L with mole ratio of 1 : 1. Single-crystal X-ray diffraction analysis reveals that 1 crystallizes in triclinic space group Pī with a 1-D stair-like structure and rich hydrogen bonding interactions expand the 1-D structure to a CsCl-like 8-connected topology. Magnetic properties of 1 have been studied showing antiferromagnetic exchange interaction between Co(II) ions.

Acknowledgments

We are grateful to the Natural Science Foundation of China (No. 21201126) and “Educational Commission of Sichuan Province (12ZA106) 211 project” Special Fund of Sichuan Agricultural University.

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