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Journal of Coordination Chemistry Volume 66, 2013 - Issue 7
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Original Articles

Self-assembly of a 3-D self-catenated framework based on [V4O12]4− polyoxoanions and cobalt-organic polymer

Yan-Fei Qi School of Public Health, Jilin University, Changchun, ChinaCorrespondence[email protected]
,
Kun Xu School of Public Health, Jilin University, Changchun, China
,
Li-Jun Lu JiLin Entry-Exit Inspection and Quarantine Bureau, Changchun, China
,
Juan Li School of Public Health, Jilin University, Changchun, ChinaCorrespondence[email protected]
&
En-Bo Wang Key Laboratory of Polyoxometalates Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, China
Pages 1228-1237 | Received 15 Nov 2012, Accepted 30 Jan 2013, Published online: 05 Apr 2013
 
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Abstract

Reaction of a flexible ligand with cobalt salt in the presence of polyoxovanadate produces a new composite solid, Co2(btx)4V4O12, 1 (btx = 1,4-bis(triazol-1-ylmethyl)benzene). The structure of 1 was determined by single-crystal X-ray diffraction analysis and further characterized by elemental analysis, IR spectrum, and TG analysis. Compound 1 exhibits a 3-D 4,6-connected self-catenated net constructed from [V4O12]4− building blocks and the {Co(btx)2}2+ 3-D metal-organic cation polymer. The electronic properties of 1 have been investigated.

Acknowledgements

This study was financially supported by National Science Foundation of China (81072337), China Postdoctoral Science Foundation (20100481064 and 2012T50307) and S& Development Project Foundation of Jilin Province (201101057), General Administration of Quality Supervision, Inspection and Quarantine of China Project (2009IK151).

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