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Journal of Coordination Chemistry Volume 66, 2013 - Issue 8
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Articles

A new organopolymolybdate polymer for linking metal-organic moiety through Mo–N bonds

Ai-Xiang Tian Department of Chemistry, Bohai University, Jinzhou, P.R. ChinaCorrespondence[email protected]
,
Xiao-Ling Lin Department of Chemistry, Bohai University, Jinzhou, P.R. China
,
Gui-Ying Liu Liaoning Ocean and Fisheries Science Research Institute, DaLian, P.R. China
,
Ru Xiao Department of Chemistry, Bohai University, Jinzhou, P.R. China
,
Jun Ying Department of Chemistry, Bohai University, Jinzhou, P.R. China
&
Xiu-Li Wang Department of Chemistry, Bohai University, Jinzhou, P.R. China
Pages 1340-1349 | Received 21 May 2012, Accepted 12 Dec 2012, Published online: 09 Apr 2013
 
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Abstract

A new organopolymolybdate polymer, [Zn2(H2biim)4(Hbiim)2][H2(γ-Mo8O26)]·8H2O (1) (H2biim = 2,2′–biimidazole), was synthesized under hydrothermal conditions. In 1, H2biim has chelate and linking roles. Three H2biim chelate one Zn to form a cationic metal-organic subunit; two subunits link one octamolybdate through Mo–N bonds, forming a two-supporting anion. There are abundant π…π stacking interactions between these anions inducing a 1-D supramolecular chain. The electrochemical behavior and photoluminescence of 1 have been studied.

Acknowledgments

We are thankful for the financial support from the National Natural Science Foundation of China (Nos. 21101015 and 21171025), New Century Excellent Talents in University (NCET-10-0853) and Natural Science Foundation (201102003) and Doctoral Initiation Project (No. 20111147) of Liaoning Province.

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