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Journal of Coordination Chemistry Volume 66, 2013 - Issue 12
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Articles

Syntheses, crystal structures, and luminescent properties of two cadmium(II) complexes based on bis(imidazole) and dicarboxylate

Xiao-Fang Wang Department of Chemistry, Institute of Polyoxometalate Chemistry, Northeast Normal University, Changchun, P.R. China
,
Xiao-Yang Yu Department of Chemistry, Institute of Polyoxometalate Chemistry, Northeast Normal University, Changchun, P.R. China; Jilin Institute of Chemical Technology, Jilin city, P.R. China
,
Ju-Kun Hu Department of Chemistry, Institute of Polyoxometalate Chemistry, Northeast Normal University, Changchun, P.R. China
&
Hong Zhang Department of Chemistry, Institute of Polyoxometalate Chemistry, Northeast Normal University, Changchun, P.R. ChinaCorrespondence[email protected]
Pages 2118-2128 | Received 02 Nov 2012, Accepted 04 Feb 2013, Published online: 30 May 2013
 
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Abstract

Two complexes, [Cd(ip–OH)(H2biim)(H2O)][Cd(ip–OH)(H2biim)(H2O)3]·8(H2O) (1) and [Cd(Himdc)(H2biim)] n (2) (H2ip–OH = 5-hydroxylisophthalic acid, H2biim = 2,2’-biimidazolate, H3imdc = 4,5-imidazoledicarboxylic acid), have been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction. 1 is a 3-D supramolecular network constructed by 0-D and 1-D motifs through hydrogen bonds and π⋯π interactions. Complex 2 is a 1-D zigzag polymeric coordination chain and the chains are connected to form a 3-D supramolecular network by hydrogen bonds. The complexes were characterized by elemental and thermogravimetric analyses. Fluorescence was also investigated.

Acknowledgments

This work was supported by the NSF of China (21271038, 21071027), the China High-Tech Development 863 Program (2007AA03Z218) and analysis and testing foundation of Northeast Normal University.

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