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Journal of Coordination Chemistry Volume 66, 2013 - Issue 13
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Articles

Topological diversification of two new Cd(II) photoluminescent coordination polymers via auxiliary N-donor ligands

Guilan Xu Key Laboratory of Coordination Chemistry and Functional Materials in Universities of Shandong, Dezhou University, Shandong, P.R. China
&
Feng Guo Key Laboratory of Coordination Chemistry and Functional Materials in Universities of Shandong, Dezhou University, Shandong, P.R. ChinaCorrespondence[email protected]
Pages 2398-2404 | Received 09 Aug 2012, Accepted 28 Mar 2013, Published online: 17 Jun 2013
 
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Abstract

Two new cadmium(II) coordination polymers, [Cd2(nda)2(L1)] n (1) and [Cd(nda)(L2)0.5] n (2), were hydrothermally synthesized with 1,4-naphthalenedicarboxylic acid (H2nda) and auxiliary N-donor coligands [L1 = 1,5-bis(2-methyl-imidazol-1-yl)pentane and L2 = 4,4′-bis(2-methyl-imidazol-1-ylmethyl)biphenyl]. Single-crystal X-ray diffraction analyses showed that the topological networks are different when the N-donor ligands are changed. Compound 1 showed a (416.65) topology and 2 showed a twofold interpenetrating pcu topology.

Acknowledgements

We thank the support of this work by The National Natural Science Foundation of Shandong Province (ZR2011BL024) and the financial support from Dezhou University (318019).

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