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Journal of Coordination Chemistry Volume 66, 2013 - Issue 16
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Articles

Palladium catalyzed Mizoroki–Heck and Suzuki–Miyaura reactions using naphthalenomethyl-substituted imidazolidin-2-ylidene ligands in aqueous media

Aydin Aktaşa Faculty of Science and Arts, Department of Chemistry, Inönü University, Malatya, Turkey
,
Senem Akkoçb Faculty of Science, Department of Chemistry, Erciyes University, Kayseri, Turkey
&
Yetkin Göka Faculty of Science and Arts, Department of Chemistry, Inönü University, Malatya, Turkey
Pages 2901-2909 | Received 11 Apr 2013, Accepted 29 May 2013, Published online: 24 Jul 2013
 
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Abstract

Naphthalenomethyl-substituted imidazolidinium salts (1a-g) were prepared and characterized by conventional spectroscopic methods, 1H NMR, 13C NMR, FTIR, and elemental analysis techniques. The in situ prepared three component systems naphthalenomethyl-substituted imidazolidinium salts, Pd(OAc)2, and K2CO3 catalyzed quantitatively the Mizoroki–Heck and Suzuki–Miyaura coupling of aryl halides under mild conditions in aqueous media.

Acknowledgment

This work was financially supported by Inönü University Research Fund (I.U.B.A.P. 2011/130).

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