Synthesis, crystal structure, fluorescence, electrochemical property, and SOD-like activity of an unexpected nickel(II) complex with a quinazoline-type ligand

Abstract

An unexpected mononuclear Ni(II) complex, [Ni(L²)₂]·CH₃OH (HL² = 1-(2-{[(E)-3,5-dichloro-2-hydroxybenzylidene]amino}phenyl)ethanone oxime), has been synthesized via complexation of Ni(II) acetate tetrahydrate with HL¹. HL¹ and its corresponding Ni(II) complex were characterized by IR, ¹H-NMR spectra, HRMS, as well as by elemental analysis, UV–vis, and emission spectroscopy. The crystal structure of the complex has been determined by single-crystal X-ray diffraction. Each complex links two other molecules into an infinite 1-D chain via intermolecular hydrogen bonds. Moreover, the electrochemical properties of the nickel complex were studied by cyclic voltammetry. Superoxide dismutase-like activities of HL¹ and Ni(II) complex were also investigated.

Keywords:

• Quinazoline-type ligand
• Crystal structure
• Fluorescence behavior
• Cyclic voltammetry
• Superoxide dismutase activity

Notes

We are thankful for the financial support by the Natural Science Foundation of Gansu Province [No: 1107RJZA165]; the Young Scholars Science Foundation of Lanzhou Jiaotong University [No: 2011038]; and the Innovation and Technology Fund of Lanzhou Jiaotong University [No: DXS-2013035].