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Journal of Coordination Chemistry Volume 67, 2014 - Issue 7
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Original Articles

Synthesis, structure, magnetism and antibacterial properties of a 2-D nickel(II) metal–organic framework based on 3-nitrophthalic acid and 4,4′-bipyridine

Xinyi LuState Key Laboratory of Fine Chemicals and School of Chemical Engineering, Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian, PR China
,
Junwei YeState Key Laboratory of Fine Chemicals and School of Chemical Engineering, Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian, PR ChinaCorrespondence[email protected]
,
Limei ZhaoState Key Laboratory of Fine Chemicals and School of Chemical Engineering, Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian, PR China
,
Yuan LinState Key Laboratory of Fine Chemicals and School of Chemical Engineering, Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian, PR China
&
Guiling NingState Key Laboratory of Fine Chemicals and School of Chemical Engineering, Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian, PR ChinaCorrespondence[email protected]
Pages 1133-1140 | Received 01 Nov 2013, Accepted 11 Feb 2014, Published online: 30 Apr 2014
 
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Abstract

A 2-D nickel(II) mixed-ligand metal–organic framework [Ni(NPTA)(4,4′-bipy)(H2O)]n (1) was synthesized by reaction of 3-nitrophthalic acid (H2NPTA) and 4,4′-bipyridine (4,4′-bipy) with Ni(II) under hydrothermal condition and characterized by elemental analysis, infrared spectroscopy, and single-crystal X-ray diffraction analysis. Compound 1 possesses a 2-D layer structure constructed from dinuclear nickel(II) building blocks in which two crystallographically equivalent Ni ions are bridged by two NPTA ligands. Furthermore, the layers are connected into 3-D supramolecular network by hydrogen bonds. The magnetism and antibacterial activity of 1 were investigated.

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