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Journal of Coordination Chemistry Volume 67, 2014 - Issue 15
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A new 1-D chain based on the trivacant monocapped Keggin arsenomolybdate and the copper complex linker: synthesis, crystal structure, and ESI-MS analyses

Lizhou WuKey Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, Department of Chemistry, Northwest University, Xi’an, PR China;Department of Chemistry and Chemical Engineering, Ankang University, Ankang, PR China
,
Ying MaKey Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, Department of Chemistry, Northwest University, Xi’an, PR China
,
Lijuan WangKey Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, Department of Chemistry, Northwest University, Xi’an, PR China
,
Xinbo DongKey Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, Department of Chemistry, Northwest University, Xi’an, PR China
&
Ganglin XueKey Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, Department of Chemistry, Northwest University, Xi’an, PR ChinaCorrespondence[email protected]
Pages 2595-2605 | Received 20 Apr 2014, Accepted 26 Jun 2014, Published online: 08 Sep 2014
 
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Abstract

A new organic–inorganic hybrid (H2en)2[[Cu(en)2]AsIIIAsVMoVI9O34]·6H2O (1), containing a 1-D helical chain based on the trivacant monocapped Keggin arsenomolybdate and the copper complex linker {[Cu(en)2][AsIIIAsVMoVI9O34]}n4n− (en = ethylenediamine), has been synthesized and characterized by IR spectra, TG analyses, single-crystal X-ray diffraction, and high-resolution electrospray ionization mass spectrometry (ESI-MS). Large voids are observed and a 1-D chain containing repeated (H2O)8 water units from lattice water molecules is formed along the a axis in the crystal structure. The high-resolution ESI-MS shows that the intact framework [Cu(en)2][AsIIIAsVMoVI9O34]4− exists in solution.

Graphical Abstract

Funding

This work was supported by the National Natural Science Foundation of China [Grant number 21373159] and Funded projects of Independent Innovation of Northwest University Postgraduates [Grant number YZZ12034].

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