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Journal of Coordination Chemistry Volume 68, 2015 - Issue 3
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Original Articles

Synthesis, structures and magnetic properties of two isomeric coordination polymers constructed from pamoic acid and 1,2-di(4-pyridyl)ethane

Xianzhong BuCollege of Materials and Mineral Resources, Xi’an University of Architecture and Technology, Xi’an, ChinaView further author information
,
Zongwu WeiCollege of Resources and Metallurgy, Guangxi University, Nanning, ChinaCorrespondence[email protected]
View further author information
&
Shaofeng RenSouthwest Energy and Mineral Resources Corporation Co., Ltd., Guiyang, ChinaView further author information
Pages 471-478 | Received 14 May 2014, Accepted 10 Nov 2014, Published online: 02 Jan 2015
 
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Abstract

Two isostructural compounds, [Co(pam)(bpe)(H2O)2]n (1) and [Mn(pam)(bpe)(H2O)2]n (2) (H2pam = pamoic acid, bpe = 1,2-di(4-pyridyl)ethane), have been solvothermally synthesized and characterized by elemental analyses, IR, and powder X-ray diffraction. Single-crystal X-ray analysis reveals that 1 and 2 are isostructural and feature a threefold interpenetrated cds topological framework. Magnetic investigations reveal that both 1 and 2 exhibit antiferromagnetic properties.

Presented here are two isomeric compounds constructed from pamoic acid and 1,2-di(4-pyridyl)ethane, which are 3-D frameworks with threefold interpenetrated cds topology.

Additional information

Funding

This work was supported by Guangxi Science and Technology Project [grant number 1355002-1], the Natural Science Basic Research Plan in Shaanxi Province of China [grant number 2013JM7024], and China Postdoctoral Science Foundation funded project [grant number 2013M541935].

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