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Transition metal complexes with cage-opened diamondoid tetracyclo[7.3.1.1^4,12.0^2,7]tetradeca-6.11-diene

Lars ValentinInstitute of Inorganic and Analytical Chemistry, Justus-Liebig University, Gießen, Germany

Anja HenssInstitute of Inorganic and Analytical Chemistry, Justus-Liebig University, Gießen, Germany

Boryslav A. TkachenkoInstitute of Organic Chemistry, Justus-Liebig University, Gießen, Germany

Andrey FokinDepartment of Organic Chemistry, Kiev Polytechnic Institute, Kiev, Ukraine

Peter R. SchreinerInstitute of Organic Chemistry, Justus-Liebig University, Gießen, Germany

Sabine BeckerInstitute of Inorganic and Analytical Chemistry, Justus-Liebig University, Gießen, Germany

Christian WürteleInstitute of Inorganic and Analytical Chemistry, Justus-Liebig University, Gießen, Germany

Siegfried SchindlerInstitute of Inorganic and Analytical Chemistry, Justus-Liebig University, Gießen, GermanyCorrespondence[email protected]

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Abstract

Cage-opened diamondoid tetracyclo[7.3.1.1^4,12.0^2,7]tetradeca-6,11-diene forms complexes with AgNO₃ and CuCl. The latter crystallized from acetonitrile in polymeric form [Cu₂Cl₂(CH₃CN)(diene)]_n; in the presence of 2,2′-bipyridine, a double-charged monomeric Cu(I)-complex [Cu₂(bipy)₂(diene)]²⁺ formed. Both complexes were structurally characterized through X-ray crystal diffraction analysis.

Graphical abstract

Copper(I) complexes with the diamantane diene tetracyclo[7.3.1.1^4,12.0^2,7]tetradeca-6.11-diene (6) have been prepared and an interesting crystal structure, [Cu₂(bipy)₂(6)]²⁺ (hydrogen atoms, anions, and solvent molecules are omitted for clarity), was obtained.

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Notes

Dedicated to the 70th birthday of Rudi van Eldik.

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Related Research Data

CCDC 1057184: Experimental Crystal Structure Determination

Source: Cambridge Crystallographic Data Centre

CCDC 1056381: Experimental Crystal Structure Determination

Source: Cambridge Crystallographic Data Centre

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Transition metal complexes with cage-opened diamondoid tetracyclo[7.3.1.14,12.02,7]tetradeca-6.11-diene

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Transition metal complexes with cage-opened diamondoid tetracyclo[7.3.1.1^4,12.0^2,7]tetradeca-6.11-diene