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Journal of Coordination Chemistry Volume 70, 2017 - Issue 7
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Articles

Using experimental methods and CSD data for investigating the products of the reaction between 2-((2-aminoethyl)amino)ethanol with CdI2 and CdI2/HgI2-mixtures

Mohammad HakimiChemistry Department, Payame Noor University, Tehran, I. R. IranCorrespondence[email protected]
,
Zahra MardaniChemistry Department, Urmia University, Urmia, I. R. Iran
,
Keyvan MoeiniChemistry Department, Payame Noor University, Tehran, I. R. Iran
,
Nourollah FeiziChemistry Department, Payame Noor University, Tehran, I. R. Iran
&
Fabian MohrFakultät für Mathematik und Naturwissenschaften - Anorganische Chemie, Bergische Universität Wuppertal, Wuppertal, Germany
Pages 1247-1259 | Received 12 Apr 2016, Accepted 16 Feb 2017, Published online: 13 Mar 2017
 
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Abstract

The binding modes of 2-((2-aminoethyl)amino)ethanol-based ligands were explored using the Cambridge Structural Database (CSD). To extend this field, a new cadmium complex containing 2-((2-aminoethyl)amino)ethanol (AEAE), [Cd(AEAE)2][Cd(AEAE)2]′[CdI4]2 (1), was prepared and characterized by spectroscopic methods and single-crystal X-ray diffraction. The reaction of AEAE with a 1:1 mixture of CdI2 and HgI2 was also investigated. The complex, [Cd(AEAE)2][I2Hg(μ-I2)2HgI2] (2), was synthesized and characterized. Compounds 1 and 2 represent the first tridentate binding modes of an AEAE type ligand with Cd2+. Geometrical investigation for complexes containing Cd(Namine2Oalcohol)2, CdIn, and HgIn environment were carried out using the CSD software. Also different possible diastereomers which can be formed in coordination of a pair of tridentate AEAE ligands in octahedral geometry were studied and discussed.

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