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Journal of Coordination Chemistry Volume 70, 2017 - Issue 12
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Synthesis, characterization, and properties of four lanthanide-based coordination polymers with mixed ligands of 4-((4′-carboxybenzyl)oxy)benzoic acid and oxalic acid

Wen-Xian ChenInstitute of Industrial Catalysis, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, P.R. ChinaCorrespondence[email protected]
,
Xiang ZhouInstitute of Industrial Catalysis, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, P.R. China
,
Yi-Fen GaoInstitute of Industrial Catalysis, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, P.R. China
,
Qiu-Ping LiuInstitute of Industrial Catalysis, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, P.R. China
&
Gui-Lin ZhuangInstitute of Industrial Catalysis, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, P.R. ChinaCorrespondence[email protected]
Pages 2029-2039 | Received 03 May 2016, Accepted 22 Apr 2017, Published online: 14 May 2017
 
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Abstract

A series of lanthanide-based coordination polymers (Ln2(CBOB)2(OX)·H2O, where Ln = Gd (1), Eu (2), Pr (3), and Tb (4); CBOB = 4-[(4′-carboxybenzyl)oxy]benzoate; OX = oxalate), were obtained from the reaction of H2OX, H2CBOB, and Ln(NO3)3 with the metal salts. Single-crystal measurements show that both 1 and 2 feature unique 3-D structures with the [Ln(COO)n(C2O4)m] layers connected by CBOB ligands. Moreover, 1, 3, and 4 are antiferromagnetic and 2 and 4 display obvious luminescence emission peaks. Furthermore, quantum Monte Carlo (QMC) simulations and the experimental results reveal that the magnetic coupling parameters of adjacent Gd(III) ions in 1 are −0.026(2) and −0.0069(3) cm─1.

Acknowledgement

We gratefully thank Prof. La-sheng Long of Xiamen University for kind help.

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