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Journal of Coordination Chemistry Volume 70, 2017 - Issue 19
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Articles

Tetrazoleacetic acid templated 3d-4f heterometallic-organic frameworks constructed from different ligands: structures, luminescence, magnetism and photocatalytic properties

Lin-Xia ZhouJoint Laboratory for Environmental Test and Photocatalytic Research of Ningbo University-Zhejiang Zhonghao Applied Engineering Technology Institute Co., Ltd., Ningbo University, Ningbo, P. R. China
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Jian-Qing XuJoint Laboratory for Environmental Test and Photocatalytic Research of Ningbo University-Zhejiang Zhonghao Applied Engineering Technology Institute Co., Ltd., Ningbo University, Ningbo, P. R. China;Research Center of Applied Solid State Chemistry, Chemistry Institute for Synthesis and Green Application, Ningbo University, Ningbo, P. R. China
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Yue-Qing ZhengJoint Laboratory for Environmental Test and Photocatalytic Research of Ningbo University-Zhejiang Zhonghao Applied Engineering Technology Institute Co., Ltd., Ningbo University, Ningbo, P. R. China;Research Center of Applied Solid State Chemistry, Chemistry Institute for Synthesis and Green Application, Ningbo University, Ningbo, P. R. ChinaCorrespondence[email protected]
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Hong-Lin ZhuJoint Laboratory for Environmental Test and Photocatalytic Research of Ningbo University-Zhejiang Zhonghao Applied Engineering Technology Institute Co., Ltd., Ningbo University, Ningbo, P. R. China;Research Center of Applied Solid State Chemistry, Chemistry Institute for Synthesis and Green Application, Ningbo University, Ningbo, P. R. China
Pages 3379-3393 | Received 13 Mar 2017, Accepted 01 Sep 2017, Published online: 14 Oct 2017
 
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Abstract

A series of 3-D lanthanide-transition 3d-4f heterometallic complexes have been synthesized by hydrothermal route from mixtures of 2,2′-bipyridyl-5,5′-dicarboxylic acid (H2bpdc) and acetic acid (HAc) with tetrazoleacetic acid as template. The single-crystal X-ray analysis shows that nine CdLn(H2O)2Cl2(bpdc)Ac complexes (Ln = La for 1, Pr for 2, Nd for 3, Sm for 4, Eu for 5, Gd for 6, Dy for 7, Ho for 8, Er for 9) crystallized in the space group P-1 and featured three-nodal (3, 4, 6)-three connected topological frameworks. The photocatalytic behaviors imply that 1–9 have significant photocatalytic activities for degradation of RhB.

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