Advanced search
Publication Cover
Journal of Coordination Chemistry Volume 71, 2018 - Issue 15
Submit an article Journal homepage
160
Views
22
CrossRef citations to date
0
Altmetric
Articles

Synthesis, characterization, and structural studies of two heteroleptic Mn(II) complexes with tridentate N,N,N-pincer type ligand

Saied M. SolimanDepartment of Chemistry, Rabigh College of Science and Art, King Abdulaziz University, Jeddah, Saudi Arabia;Faculty of Science, Department of Chemistry, Alexandria University, Alexandria, EgyptCorrespondence[email protected]
&
Ayman El-FahamFaculty of Science, Department of Chemistry, Alexandria University, Alexandria, Egypt;Department of Chemistry, College of Science, King Saud University, Riyadh, Saudi Arabia
Pages 2373-2388 | Received 02 Feb 2018, Accepted 03 Apr 2018, Published online: 18 May 2018
 
Sample our Engineering & Technology journals, sign in here to start your access, latest two full volumes FREE to you for 14 days

Abstract

Molecular and supramolecular structures of two new Mn(II) complexes with tridentate N,N,N-pincer type ligand (L) are presented. [MnL(H2O)2Cl]Cl (1) and [MnL(H2O)3](NO3)2·H2O (2) have octahedral coordination environments with different degrees of distortion. The molecular packing of 1 and 2 is dominated by strong O–H⋯Cl and O–H⋯O H-bonds, respectively, as well as weak C–H⋯O interactions. The percentage of Cl⋯H and O⋯H contacts are 15.5 and 31.5% for 1 and 2, respectively, using Hirshfeld analysis. Based on atoms in molecules theory, the Mn–N, Mn–O, and Mn–Cl bonds have the characteristics of closed shell interactions. Thermal decomposition of L and its Mn(II) complexes are also presented.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Synthesis, characterization, photophysical properties, and catalytic activity of an SCS bis(N-heterocyclic thione) (SCS-NHT) Pd pincer complex
Source: Royal Society of Chemistry (RSC)
Synthesis, characterization, and structural studies of two heteroleptic Mn(II) complexes with tridentate N,N,N-pincer type ligand
Source: Figshare
CCDC 1815556: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Experimental and computational study of the interplay between C–H/π and anion–π interactions
Source: Royal Society of Chemistry (RSC)
A new class of PN3-pincer ligands for metal–ligand cooperative catalysis
Source: Elsevier BV
Hydrogen–Hydrogen Bonding: A Stabilizing Interaction in Molecules and Crystals
Source: Wiley
Shared and Closed-Shell O−O Interactions in Silicates
Source: American Chemical Society (ACS)
Intramolecular H···H Interactions for the Crystal Structures of [4-((E)-But-1-enyl)-2,6-dimethoxyphenyl]pyridine-3-carboxylate and [4-((E)-Pent-1-enyl)-2,6-dimethoxyphenyl]pyridine-3-carboxylate; DFT Calculations on Modeled Styrene Derivatives
Source: American Chemical Society (ACS)
Non-symmetric pincer ligands: complexes and applications in catalysis
Source: Royal Society of Chemistry (RSC)
Hydrogen bond strengths revealed by topological analyses of experimentally observed electron densities
Source: Elsevier BV
A topological analysis of electron density and chemical bonding in cyclophosphazenes PnNnX2n (X = H, F, Cl; n = 2, 3, 4)
Source: Pleiades Publishing Ltd
Practical applications of supramolecular chemistry
Source: Royal Society of Chemistry (RSC)
Polynuclear Complexes Containing Ditopic Bispyrazolylmethane Ligands. Influence of Metal Geometry and Supramolecular Interactions
Source: American Chemical Society (ACS)
SHELXT - Integrated space-group and crystal- structure determination
Source: International Union of Crystallography (IUCr)
Synthesis, Molecular and Supramolecular Structures of New Cd(II) Pincer-Type Complexes with s-Triazine Core Ligand
Source: MDPI AG
Distortions in Octahedrally Coordinated d 0 Transition Metal Oxides: A Continuous Symmetry Measures Approach
Source: American Chemical Society (ACS)
Four new copper(II) complexes with di-substituted s-triazine-based ligands
Source: Elsevier BV
Synthesis and structure of new 1,3,5-triazine-pyrazole derivatives
Source: Elsevier BV
A Cobalt(I) Pincer Complex with an η2 -Caryl −H Agostic Bond: Facile C−H Bond Cleavage through Deprotonation, Radical Abstraction, and Oxidative Addition
Source: Wiley-Blackwell
Cobalt PNC ‘pincers’: ligand dearomatisation, formation of dinuclear and N complexes and promotion of C–H activation
Source: (:unav)
sym-Trisubstituted 1,3,5-Triazine Derivatives as Promising Organic Corrosion Inhibitors for Steel in Acidic Solution
Source: MDPI AG
Highly Selective Molybdenum ONO Pincer Complex Initiates the Living Ring-Opening Metathesis Polymerization of Strained Alkynes with Exceptionally Low Polydispersity Indices
Source: American Chemical Society (ACS)
CCDC 1815557: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
The characterization of atomic interactions
Source: AIP Publishing
A new supramolecular net constructed with 2D (4,4) layer subunits displaying unique 4-connected msw/P42/nnm topology: Structure, fluorescence and catalytic properties
Source: Elsevier BV
Chemistry - A European Journal
Source: Wiley
Bonded-atom fragments for describing molecular charge densities
Source: Springer Science and Business Media LLC
Effect of Solvent upon CH···O Hydrogen Bonds with Implications for Protein Folding
Source: American Chemical Society (ACS)
One pot synthesis of two Mn(II) perchlorate complexes with s -triazine NNN -pincer ligand; molecular structure, Hirshfeld analysis and DFT studies
Source: Elsevier BV
Crystalline-State Guest-Exchange and Gas-Adsorption Phenomenon for a “Soft” Supramolecular Porous Framework Stacking by a Rigid Linear Coordination Polymer
Source: American Chemical Society (ACS)
Frontiers of supramolecular chemistry at solid surfaces
Source: Royal Society of Chemistry (RSC)
Angewandte Chemie International Edition
Source: Wiley
Long-range corrected hybrid density functionals with damped atom–atom dispersion corrections
Source: Royal Society of Chemistry (RSC)
Synthesis, characterization, and structural studies of two heteroleptic Mn(II) complexes with tridentate N,N,N-pincer type ligand
Source: Figshare
Synthesis, characterization and structural studies of two heteroleptic Mn(II) complexes with tridentate N,N,N-pincer type ligand
Source: Figshare
Pd( ) pincer type complex catalyzed tandem C–H and N–H activation of acetanilide in aqueous media: a concise access to functionalized carbazoles in a single step
Source: (:unav)
Highly porous Co(ii)-salicylate metal–organic framework: synthesis, characterization and magnetic properties
Source: Royal Society of Chemistry (RSC)
Structural analyses of two new highly distorted octahedral copper(II) complexes with quinoline-type ligands; Hirshfeld, AIM and NBO studies
Source: Elsevier BV
Underlying nets in three-periodic coordination polymers: topology, taxonomy and prediction from a computer-aided analysis of the Cambridge Structural Database
Source: Royal Society of Chemistry (RSC)
Mechanism of the oxidative addition of hypervalent iodonium salts to palladium(II) pincer-complexes☆
Source: Elsevier BV
Second Ligand-Directed Assembly of Photoluminescent Zn(II) Coordination Frameworks
Source: American Chemical Society (ACS)
Pincer-Type Complexes for Catalytic (De)Hydrogenation and Transfer (De)Hydrogenation Reactions: Recent Progress
Source: Wiley

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.