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Articles

A 3-D porous NiII coordination polymer constructed from oxalate and hydrazine linkers

, , , , , , & show all
Pages 1097-1105 | Received 29 Jun 2019, Accepted 23 Apr 2020, Published online: 13 May 2020
 

Abstract

A NiII-MOF, {[Ni(C2O4)(N2H4)]·2H2O}n (1), was constructed by oxalate and hydrazine under hydrothermal conditions at 130 °C. Single-crystal X-ray structural analysis indicates that 1 has a 3-D porous architecture with (103) topology based on two kinds of 1-D zigzag [Ni(C2O4)]n chains with the same structure but different extension directions in the ab plane separated by N2H4 linker. 1 reveals antiferromagnetic behavior and thermal stability below 283 °C.

Graphical Abstract

Disclosure statement

No potential conflict of interest was reported by the authors.

Additional information

Funding

This work is financially sponsored by the National Nature Science Foundation of China [Nos. 21461003 and 21361003], the Guangxi Natural Science Foundation [Nos. 2016GXNSFFA380010, 2016GXNSFAA380206, 2016GXNSFBA380237, 2018GXNSFBA281197, and 2018GXNSFAA294060], the project of basic ability elevation of middle-aged and young teachers of Guangxi Colleges and Universities [Nos. 2018KY0580 and 2020KY19017], and Guangxi Colleges and Universities Key Subject of Material Physics and Chemistry [Nos. KS17ZD02 and KS16ZD04].

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