Abstract
Earth-abundant transition metals could be used as a noble metal replacement in catalysis not only for different catalytic reactivity but environmentally benign methodology. We report here on the iron-catalyzed synthesis of N-alkylated amines via borrowing hydrogen strategy and differently functionalized aniline derivatives are alkylated in good yields.
Graphical Abstract
![](/cms/asset/92b07c38-97fe-4160-bf7c-f5e8a7511aaa/gcoo_a_1881066_uf0001_b.jpg)
Acknowledgment
We are grateful to the National Natural Science Foundation of China (22001060), Henan Youth Support Talent Project (2021HYTP005), Scientific Research and Development Project of Henan Academy of Sciences (200403001, 200503001, 200603035, 200603041, 200603108) and Outstanding Youth Training Program of Henan Academy of Sciences (190403004) for support of this research.
Disclosure statement
The authors declare no competing financial interest.
Table 2. Scope of anilines.
Table 3. Scope of primary alcohols.