STEREOCHEMISTRY OF COMPLEXES OF MULTIDENTATE LIGANDS

IV¹ Stereoselective cobalt(III) ion complexes of 1,7-bis(2-S-pyrrolidyl)-2,6-diazaheptane

Moo-Jin Jun Department of Chemistry, University of Illinois at Chicago Circle, Box 4348, Chicago, Illinois, 60680

Chui Fan Liu Department of Chemistry, University of Illinois at Chicago Circle, Box 4348, Chicago, Illinois, 60680

Abstract

Dichloro, dinitro, and diacetato cobalt(III) complexes of a new tetramine ligand, 1,7-bis(2-S-pyrrolidyl)-2,6-diazaheptane (SS-pyht) have been prepared and characterized. Only the trans isomer has been obtained for each complex. Oxalate ion reacts with trans-[Co(SS-pyht)Cl₂]ClO₄ in aqueous media to produce A-cis-β-[Co(SS-pyht)Ox]ClO₄.

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STEREOCHEMISTRY OF COMPLEXES OF MULTIDENTATE LIGANDS

IV¹ Stereoselective cobalt(III) ion complexes of 1,7-bis(2-S-pyrrolidyl)-2,6-diazaheptane

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STEREOCHEMISTRY OF COMPLEXES OF MULTIDENTATE LIGANDS

IV1 Stereoselective cobalt(III) ion complexes of 1,7-bis(2-S-pyrrolidyl)-2,6-diazaheptane

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IV¹ Stereoselective cobalt(III) ion complexes of 1,7-bis(2-S-pyrrolidyl)-2,6-diazaheptane