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Original Articles

MONOCYCLOPENTADIENYLMOLYBDENUM(III) CHEMISTRY

Pages 121-173 | Received 26 May 1992, Accepted 05 Sep 1992, Published online: 23 Sep 2006
 

Abstract

The synthesis, structure, properties, and reactivity of complexes of Mo(III) containing one cyclopentadienyl or substituted cyclopentadienyl ring are reviewed. In particular, the electronic structure of mononuclear (radical) compounds and the synergistic stabilization through interactions are discussed, as well as the effect of these interactions on the molecular structure and on the redox potentials of the compounds.

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