614
Views
11
CrossRef citations to date
0
Altmetric
Original Articles

ELECTRICAL PROPERTIES OF SILICONE OIL-WATER INTERFACE IN THE PRESENCE OF IONIC SURFACTANTS AND SALT: IMPORTANCE IN THE STABILITY OF OIL-IN-WATER EMULSIONS

&
 

Abstract

Silicone oil emulsions are used in a variety of industries. Electrical properties of the oil-water interface play a very important role in the stability of these emulsions. This work reports studies on the stability of silicone oil-water emulsions in the presence of ionic surfactants and salt. It was found that the addition of salt has a profound effect on the electrical properties of the interface. The kinetics of the growth of oil droplets in the emulsion was studied in emulsions containing a low volume fraction of silicone oil. The growth of droplets followed second-order kinetics commensurate with binary coalescence of droplets. It was found that the surfactant concentration and the presence of salt had a significant effect on the size of the droplets as well as their rate of growth. The stability of emulsions was correlated with the electrical properties of the oil-water interface and adsorption of surfactant molecules at the interface.

Notes

*Present affiliation: Department of Chemical Engineering, BMS College of Engineering, Bangalore, India.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.