Abstract
Equilibrium characteristics of water vapor adsorption on microporous silica gel and macroporous fly ash are investigated in the presence of corona discharges. The discharge is produced at a fine wire surface in a wire-cylinder electrode geometry, with the adsorbent sample placed in the inter-electrode space. A significant reduction in water vapor adsorption capacity is observed for both negative and positive coronas. Heat effects appear to be negligible. To provide a theoretical understanding of the altered equilibrium, three distinct mechanisms are proposed and evaluated. One mechanism, in particular, is seen to hold much promise.