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Letters

Rigid Backbone Polymers, XIII: Effects of the Nature of the Solvent on the Lyotropic Mesomorphicity of Cellulose Acetate

Pages 237-241 | Received 21 Dec 1979, Published online: 20 Apr 2011
 

Abstract

The behavior of cellulose acetate was studied in over 30 solvents. It was found that the concentration C* at which the anisotropic phase appears, is dependent on the nature of the solvent. In strong or moderately strong acids, C* is linearly dependent on pK, that is, the stronger the acid the lower the concentration at which anisotropy makes its first appearance. In other solvents, C* is inversely dependent on the molar volume of the solvent.

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