Electrocrystallization as a Rechargeable Organic Battery

Takashi Nogami Department of Applied Chemistry, Faculty of Engineering, Osaka University, Yamada-oka, Suita, Osaka, 565, Japan

Shigeo Ohnishi Department of Applied Chemistry, Faculty of Engineering, Osaka University, Yamada-oka, Suita, Osaka, 565, Japan

Yoshihiko Tasaka Department of Applied Chemistry, Faculty of Engineering, Osaka University, Yamada-oka, Suita, Osaka, 565, Japan

Hiroshi Mikawa Department of Applied Chemistry, Faculty of Engineering, Osaka University, Yamada-oka, Suita, Osaka, 565, Japan

Abstract

Electrocrystallization of conductive organic salts can be regarded as a charging process of a secondary battery. By use of a lithium metal as an anode, the following two organic batteries were made after electrocrystallization, i.e., Li|LiClO₄ in THF|(perylene)-ClO₄, and Li|LiClO₄ in THF|(tetrathianaphthalene) ClO₄. All-solid state organic battery, Li|poly(ethylene oxide) + LiClO₄|(tetrathianaphthalene). ClO₄, was always made. Their charge and discharge characteristics were discussed.

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Electrocrystallization as a Rechargeable Organic Battery

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Electrocrystallization as a Rechargeable Organic Battery

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