New Class of Photo-induced Cooperative Phenomena in Organic and Inorganic Hybrid Complexes

Y. Ogawa Department of Materials Science, Graduate School of Science and Engineering, Tokyo Institute of Technology 2-12-1 Oh-okayama, Meguru-ku, Tokyo, 152-8551, Japan

S. Koshihara Department of Materials Science, Graduate School of Science and Engineering, Tokyo Institute of Technology 2-12-1 Oh-okayama, Meguru-ku, Tokyo, 152-8551, Japan; Kanagawa Academy of Science and Technology (KAST) KSP Building, 3-2-1 Sakado, Takatsu-ku, Kawasaki, 213-0012, Japan

M. Takesada Kanagawa Academy of Science and Technology (KAST) KSP Building, 3-2-1 Sakado, Takatsu-ku, Kawasaki, 213-0012, Japan

T. Ishikawa Department of Materials Science, Graduate School of Science and Engineering, Tokyo Institute of Technology 2-12-1 Oh-okayama, Meguru-ku, Tokyo, 152-8551, Japan; Kanagawa Academy of Science and Technology (KAST) KSP Building, 3-2-1 Sakado, Takatsu-ku, Kawasaki, 213-0012, Japan

Abstract

We review experimental results which show the occurrence of a new class of cooperative photo-effect so called as photo-induced phase transition (PIPT) in metal-organic hybrid system. We focus on the photo-induced spin state phase transition in spin crossover complex, and report the dynamic behavior and magnetic field effect on it. Obtained results demonstrate that cooperative spin-lattice interaction in crystal plays a key role for driving PIPT phenomena in spin crossover complexes.

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New Class of Photo-induced Cooperative Phenomena in Organic and Inorganic Hybrid Complexes

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New Class of Photo-induced Cooperative Phenomena in Organic and Inorganic Hybrid Complexes

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