Hierarchic Natures and Dynamics of Photoinduced Structural Phase Transition in Non-Degenerate Charge Density Wave States Via Successive Photoexcitations

Abstract

We investigate the adiabatic and dynamical natures of the lattice relaxation of excitons in strongly coupled electron-phonon (e-ph) systems using the extended Peierls-Hubbard model, so as to clarify the possible mechanisms of the photoinduced structural phase transition (PISPT) via multi-photon. Focusing on the growth process of relaxed domains that is induced by multi-photoexcitation, we calculate the adiabatic potential energy surfaces relevant to the nonlinear lattice relaxations of excitons in this process. Calculated potentials lead to an essential model of a multi-stepwise potential-crossing (MSPC) system that is composed of many displaced harmonic oscillators as an elementary process of the domain growth in the strongly coupled e-ph systems. We also investigate the dynamical natures in such MSPC systems calculating the time-developments the excited wave packet in this system using the density operator. It is concluded from calculated results that the system possibly develops from the lowest-energy potential state to the higher ones by the effect of the photoexcitations followed by the lattice relaxations.

Keywords:

• Photoinduced Structural Phase Transition
• Non-degenerate Charge Density Wave
• Adiabatic Potential Energy Surface
• Dynamics In Excited State