The hydrogen bond under pressure

Abstract

The hydrogen bonds are quite pervasive in several classes of materials. Its parameters are known to show systematic variations with hydrogen bond length, and pressure variable is thus a natural way for studying hydrogen bonded substances. In this article, we review the unifying features as obtained through several experimental and theoretical investigations. Amongst other things, it is examined whether the observed pressure-induced variations in parameters of hydrogen bonds are consistent with the co-relations known on different chemical substances at normal pressure. In particular, the controversies on variations of O–H and H- - -O pairs with pressure and symmetrization of hydrogen bond have been resolved. The effects of close packing promoted by pressure such as formation of muli-centered hydrogen bonds and steric repulsions and the way the hydrogen bonds counter these in different ways are also examined.

Keywords:

• pressure
• hydrogen bond
• symmetrization
• correlations
• H- - -H repulsion

Acknowledgment

We thank Dr R. Chidambaram for useful discussions.