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Phase Transitions
A Multinational Journal
Volume 81, 2008 - Issue 11-12
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Original Articles

Dipolar phases in liquid crystals with the chiral part based on the lactic acid

, , , &
Pages 963-970 | Received 18 May 2008, Accepted 02 Jun 2008, Published online: 04 Dec 2010
 

Abstract

New lactic acid derivatives exhibit paraelectric SmA and TGBA phases, ferroelectric SmC* and TGBC phases and antiferroelectric phases, the TGB and antiferroelectric phases being unusually broad. The polymorphism depends on the number of lactate units in the chiral chain and on the length of the non-chiral chain. The dielectric spectroscopy revealed the characteristic modes in all these phases. In phases with the dipolar order the spontaneous polarization and the tilt angle have been determined.

Acknowledgement

This work was supported by Projects No. IAA100100710 from Grant Agency of the Academy of Sciences of the Czech Republic, Project Czech-Polish bilateral collaboration program No. 8 (2006-2007) and OC 175 program under the Ministry of Education, Youth and Sports of the Czech Republic.

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