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Phase Transitions
A Multinational Journal
Volume 89, 2016 - Issue 9
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Original Articles

A study on polymorphism of hydrogen-bonded thermotropic liquid crystals

, , &
Pages 928-943 | Received 20 Aug 2015, Accepted 15 Oct 2015, Published online: 11 Dec 2015
 

Abstract

A novel mesogenic homologous series comprising of eight hydrogen-bonded liquid crystalline complexes are isolated and analyzed by forming a hydrogen bond between p-n alkyloxy benzoic acids (where n represent alkyloxy carbon number which varies from 5 to 12) and mesaconic acid, respectively. Eight synthesized complexes are subjected to Fourier transform infra-red spectroscopy, polarizing optical microscopy and differential scanning calorimetry studies to meet the basic characterization. The variation of optical tilt angle with respect to temperature in various conventional and smectic X phases are investigated and analyzed. A phase diagram is constructed to elucidate the mesogenic behavior of novel liquid crystalline series. The Cox ratio that reveals the order of various mesophases and the stability factor, to invoke the thermal stability of mesophases, is studied under the results of DSC thermogram.

Acknowledgements

Perpetual blessings of Lordess Bannari Amman to carry out the research work and infrastructural support provided by Bannari Amman Institute of Technology are gratefully acknowledged.

Disclosure statement

No potential conflict of interest was reported by the authors.

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