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Articles

The Influence of Pb(Mg1/3Nb2/3)O3-doping on the thermoelectric properties of BaTiO3 ceramics

, , , , &
Pages 1036-1043 | Received 07 May 2018, Accepted 25 Jul 2018, Published online: 09 Aug 2018
 

ABSTRACT

The low-lead (1-x)Pb(Mg1/3Nb2/3)O3-xBaTiO3 (x = 0, 0.025, 0.05, 0.075, 0.10 and 0.15) ceramics were fabricated by a two-step solid-state reaction route. The X-ray diffraction characterization confirms a perovskite crystal structure with tetragonal symmetry at room temperature (except for x = 0.15). SEM images indicate that all ceramic samples are dense and compact, with the grain size of 2–6 μm. Along with the increase of Pb(Mg1/3Nb2/3)O3 content, the electrical conductivity increases, and the Seebeck coefficient and the thermal conductivity decrease. With increasing temperature, σ and α increase and κ decreases. In general, adding Pb(Mg1/3Nb2/3)O3 to BaTiO3 leads to an improvement of the thermoelectric figure of merit ZT. The results are explained on the basis of structural, morphological and compositional changes.

Disclosure statement

No potential conflict of interest was reported by the author(s).

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