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Phase Transitions
A Multinational Journal
Volume 24-26, 1990 - Issue 1
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Original Articles

Theory for the transition from van der waals to metallic bonding in small (Mercury) clusters

G. M. Pastor Institut für Theoretische Physik, Freie Universität Berlin, Arnimallee 14, D-1000, Berlin 33, W. Germany
,
P. Stampfli Institut für Theoretische Physik, Freie Universität Berlin, Arnimallee 14, D-1000, Berlin 33, W. Germany
&
K. H. Bennemann Institut für Theoretische Physik, Freie Universität Berlin, Arnimallee 14, D-1000, Berlin 33, W. Germany
Pages 371-373 | Received 01 May 1989, Published online: 19 Aug 2006
 
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Abstract

A simple model is proposed to explain the recently observed size-dependence of the ionization-potential of small Hg-clusters. Delocalization of the s, p electron hole is estimated to occur for clusters with more than 13 atoms.

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