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Phase Transitions
A Multinational Journal
Volume 33, 1991 - Issue 1-4
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Part XII liquid crystals

A theory of the phase diagram around the N–A–C point in liquid crystals

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Pages 261-265 | Received 18 Mar 1990, Published online: 19 Aug 2006
 

Abstract

A phenomenological model is proposed for the nematic-smectic A–smectic C transition. Two order parameters which are biquadratically coupled are involved. The first one is primary and characterizes the appearance of layers in the smectic phases. The second order parameter is triggered by the first one and can be identified with the tilt angle.

Analytic expressions are obtained for lines and points in the phase diagram. These expressions are used to reconstruct completely the non-equilibrium Landau potential.

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