Contribution of X-Ray diffraction to the study of spin transitions in some iron (II) complexes

B. Gallois Laboratoire de Cristallographie et de Physique Cristalline (URA 144 CNRS), Université de Bordeaux I, 33405, Talence Cédex, France

T. Granier Laboratoire de Cristallographie et de Physique Cristalline (URA 144 CNRS), Université de Bordeaux I, 33405, Talence Cédex, France

F. Suez-Panama Laboratoire de Cristallographie et de Physique Cristalline (URA 144 CNRS), Université de Bordeaux I, 33405, Talence Cédex, France

J. A. Real Departemento de Quimica Inorganica, Universidad de Valencia, 46010, Valencia, España

J. Zarembowitch Laboratoire de Chimie Inorganique, (URA 420—CNRS), Université de Paris Sud, 91405, Orsay Cédex, France

Abstract

A review of recent single crystal investigations under constraint of iron (II) spin crossover complexes is given. The systems covered are Fe L₂ (NCS)₂ complexes (L = Phen, Btz) and some analogous derivatives. Emphasis is laid on the correlations between structural changes associated with spin transitions and the experimentally determined characteristics of these transitions.

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Contribution of X-Ray diffraction to the study of spin transitions in some iron (II) complexes

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Contribution of X-Ray diffraction to the study of spin transitions in some iron (II) complexes

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