The McMillan parameter as an effective field variable for the nematic–smectic tricritical point in NO.M compounds

Abstract

The dependence of the coupling of orientational and translational order parameters on the nematic-smectic A tricritical point (TCP), observed through birefringence experiments in the pure compounds and in the binary mixtures in the homologous series of N(p-n-alkyloxybenzylidene)p-n-alkylanilines, results in a mean field tricritical exponent. The McMillan parameter, M = T _NA/T _NI (where T _NA and T _NI are the smectic A—nematic (AN) and the nematic—isotropic (NI) phase transition temperatures respectively), is used as an effective and relevant field variable in analysing the TCP. The observed linear dependence of the jump in the orientational order parameter with new density variables in the tricritical region is found to be consistent with the results obtained from both the Landau mean field and the decoupled mean field models. The width of the mean field tricritical region is discussed in terms of the McMillan parameter. Further, the McMillan parameter is observed to be characteristic of chemical composition at the NA tricritical point.