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Original Articles

Anomalous viscosity of CsxCsI1−x molten alloys in the metallic composition range

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Pages 643-656 | Received 09 Feb 1984, Accepted 10 May 1985, Published online: 13 Sep 2006
 

Abstract

The kinematic viscosity v of Cs x CsI1-x molten materials has been measured in the metallic range, i.e. at small CsI molar fractions, at temperatures above the liquidus line of the phase diagram. The temperature dependence of the viscosity is of the Arrhenius type. Dissolution of salt in the metal reduces the viscosity in an unexpected manner. A quantitative analysis of the results is given in terms of a hard-sphere model involving the free-volume formalism of Cohen and Turnbull (1959, 1970) and the one-component plasma (OCP) model of Pollock and Hansen (1973) previously used by one of the authors to account for neutron diffraction results.

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