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Original Articles

Ion transport and relaxation studied by high-frequency conductivity and quasi-elastic neutron scattering

Pages 1025-1034 | Accepted 15 Dec 1990, Published online: 20 Aug 2006
 

Abstract

The experimental tools, that is frequency-dependent conductivity and quasi-elastic neutron scattering, are briefly outlined. Spectra are then presented, and the dynamic information is read from them. As a result, the elementary steps of translational motion of ions in solids can be described on atomic scales of space and time. Emphasis is put on clear-cut examples. Dispersive radio and microwave conductivity spectra are indicative of marked deviations from random jump diffusion. Spectra of this kind are typically found in structurally disordered solid electrolytes. A self-consistent explanation is provided by the process of jump relaxation.

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