Abstract
Ion-beam-assisted phase transformation in the Fe-N system has been studied in Fe samples implanted with N. By bombarding with Ar ions at temperatures in the 140°C ≤ T ≤ 420°C range, the ε-Fe2N → ε-Fe2+x N + ε-Fe3.2N and ε-Fe3.2N + γ′-Fe4N phase transformations were induced. The ion-assisted phase transformations were studied as a function of firstly the temperature of the substrate, secondly the initial N concentration and thirdly the irradiation time. The results of the experiments show that the concomitant use of ion bombardment and temperature induces a given phase transformation at a temperature that is typically 40–50°C lower than that required for thermal annealing alone.