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Original Articles

Structure and luminescence properties of an amorphous hydrogenated carbon

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Pages 369-386 | Received 03 Apr 1996, Accepted 22 May 1996, Published online: 27 Sep 2006
 

Abstract

A low hydrogen content form of amorphous hydrogenated carbon (a-C: H) was deposited from a magnetically confined plasma, for a range of self bias voltages. The structure was characterized in terms of its density, sp3 bonding fraction, H content, and H bonding. The Tauc optical gap was found to vary from 2 to 3 eV as the negative bias voltage decreased. The density of paramagnetic centres ranged from below 1018cm∼3 to above 1020cm″3. The films are strongly photoluminescent (PL) at room temperature. Their PL properties were measured and correlated with the optical gap and defect density. The PL and the PL efficiency was found to increase strongly with optical gap.

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