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Original Articles

Determination of the Monodisperse Mark-Houwink Equation of High-Vinyl Polybutadiene by Gel Chromatography and Light Scattering

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Pages 1405-1422 | Published online: 06 Dec 2006
 

Abstract

Gel chromatographic, light scattering, viscosimetric and osmotic pressure measurements have been made for high vinyl polybutadiene fractions and whole polymer. Three alternative methods for deducing a monodisperse Mark-Houwink equation from gel chromatographic, light scattering and viscosimetric data of samples with unequal distribution widths are suggested. The monodisperse Mark-Houwink equations obtained by these methods for high vinyl poly(butadiene) are all alike.

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