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Original Articles

Effects of Solute-Solvent Interactions in Liquid Adsorption Chro- Matography with Mixed Mobile Phase

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Pages 651-661 | Published online: 05 Dec 2006
 

Abstract

Two simple equations, involving formation of the multimolecular solvates in the mobile phase, are discussed. These equations define the dependence of the capacity ratio upon mobile phase composition. The LC data, available from the literature, for different alcohols chromatographed in binary mixtures of n-heptane with alkyl acetate and tetrahydrofuran on Partisil 10 at 298 K are used to examine these equations.

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