Effect of Modifier on the Retention of Solutes in Reversed-Phase Thin-Layer Chromatography

M. Bieganowska Department of Inorganic and Analytical Chemistry, Staszica 6 St., 20-081, Lublin, Poland

E. Soczewiński Department of Inorganic and Analytical Chemistry, Staszica 6 St., 20-081, Lublin, Poland

M. Waksmundzka-hajnos Department of Inorganic and Analytical Chemistry, Staszica 6 St., 20-081, Lublin, Poland

Abstract

Effect of concentration of modifier /methanol, isopropanol, acetonitrile or dioxane/ on the retention of 37 aromatic compounds with various substituents was investigated for systems of the type: silanized silica /RP-2/ - water + organic modifier. Correlations between the retention behaviour of the four modifiers are discussed.

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Effect of Modifier on the Retention of Solutes in Reversed-Phase Thin-Layer Chromatography

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Effect of Modifier on the Retention of Solutes in Reversed-Phase Thin-Layer Chromatography

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