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Original Articles

Some Aspects of Analysis of Polymers by Steric Exclusion Chromatography and On-line Low Angle Laser Light Scattering (SEC-LALLS)

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Pages 1383-1397 | Published online: 05 Dec 2006
 

Abstract

Low angle laser light scattering as a second detector for size exclusion chromatography separation leads to true values of [Mbar]W but [Mbar]n and molecular weight distribution (MWD) are strongly dependent on axial dispersion [sgrave] and calibration system. Here, we discuss (i) on certain experimental parameters and (ii) on the influence of [sgrave] for two MWD and different calibrations on [Mbar]n values and calculated MWD.

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