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Original Articles

Partition Coefficients at Infinite Dilution from Flory-Huggins Theory

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Pages 1571-1583 | Published online: 23 Oct 2006
 

Abstract

An expression relating partition coefficients at infinite dilution to Flory-Huggins interaction parameters has been derived. The equation has been successfully applied to the partitioning of alcohols between water and cellulose acetate. The solvent-solute interaction parameter has a dominant effect on partition coefficients. For the systems studied, solvent-polymer interactions appear to be negligible.

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