A New Postprocessing Strategy for Secondary Pollution: Synthesis of CdS Crystals

Abstract

Eichhornia crassipes (E.C.) is a special aquatic plant, which exhibits excellent tolerance to heavy metals and can be used for the large scale removal of heavy metals from waste water. Here the E.C was used to capture Cd²⁺, then as an in situ bio-template to successfully synthesize photoelectric CdS microcrystals. The products were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and fluorescence spectrometer. The results indicated that the peanut-like microcrystals with a length of 1.5–1.8 µm were oriented along (002) plane. The main organic groups in E.C including hydroxyl, primary amide and carboxylate played inducing and controlling roles during the formation of CdS microcrystals in the solution. The PL spectrum showed an emission peak at 450 nm and indicated that the product may have applications in an electronic light device. This approach provided an inspiration on the post-processing of the secondary pollution.

Keywords:

• CdS
• Eichhornia crassipes
• postprocessing

ACKNOWLEDGEMENTS

This work is supported by the National Science Foundation of China (91022032, 31070730, 21171001, 50973001, 20871001, and 21173001), the Important Project of Anhui Provincial Education Department (ZD2007004–1), the Science Foundation for Excellent Youth Scholars of Higher Education of Anhui Province (2011SQRL016ZD, 2009SQRZ023), 211 Project of Anhui University (2009QN012A).