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Original Articles

Determination of the Impact of Glycolate on Cs, Sr, and Actinide Separations in High-Level Waste

, , , &
Pages 2853-2865 | Received 14 Nov 2014, Accepted 26 May 2015, Published online: 08 Jan 2016
 

Abstract

The Defense Waste Processing Facility (DWPF), responsible for vitrifying high-level waste (HLW) at the Savannah River Site (SRS), is planning to introduce glycolic acid as a reductant during chemical conditioning of the waste prior to vitrification. A portion of this glycolic acid may be recycled back to the tank farm as sodium glycolate. Since glycolate can serve as a complexing agent for a variety of metallic ions, recent studies were performed to examine the effect of glycolate on the removal of Sr and actinides by monosodium titanate (MST) and modified MST (mMST) and the separation of Cs by the caustic-side solvent extraction (CSSX) process.

Additional information

Funding

The authors gratefully acknowledge Savannah River Remediation (SRR) for funding of this work.

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